Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]•H2O, a New Organically Templated Neodymium(III) Oxalate-sulfate

被引：7
|
作者：
Xu, Ning [1 ]
Xing, Yan [1 ]
Liu, Xianchun [1 ]
Song, Danhui [1 ]
Ma, Ling [1 ]
Sun, Xiujuan [1 ]
机构：
[1] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 03期
关键词：
Neodymium; Crystal engineering; Organic-inorganic hybrid composites; Luminescence; Open framework; COORDINATED ORGANONITROGEN LIGANDS; OPEN-FRAMEWORK STRUCTURES; RARE-EARTH SULFATES; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; PHOSPHITE; PILLARS; CHAINS; KAGOME; PHEN;
D O I：
10.1002/zaac.200801309
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An organically templated neodymium oxalate-sulfate [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O (1) has been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction analysis. In 1, the neodymium(III) ions are interconnected through oxalate and sulfate groups to form a neodymium oxalate-sulfate hybrid structure. A luminescence spectrum of 1 was recorded, and the luminescence decay time was also measured.
引用
收藏
页码：558 / 562
页数：5
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