Does the Temperature Dependence of the Charge Carrier Mobility in Disordered Organic Semiconductors at Large Carrier Concentrations Obey the Meyer-Neldel Compensation Law?

被引：6

作者：

Fishchuk, I. I. ^{[1
]}

Kadashchuk, A. K. ^{[2
,3
]}

Genoe, J. ^{[2
]}

Poroshin, V. N. ^{[3
]}

Baessler, H. ^{[4
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Nucl Res, Kiev, Ukraine

[2] IMEC, Heverlee, Belgium

[3] Natl Acad Sci Ukraine, Inst Phys, Kiev, Ukraine

[4] Univ Marburg, Marburg, Germany

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2011年 / 535卷 / 01期

关键词：

Charge carrier mobility; Gaussian density-of-states distribution; Mayer-Neldel rule; organic field-effect transistors; organic semiconductors; LIGHT-EMITTING-DIODES; RULE; TRANSPORT; TRANSISTORS; EXPLANATION; RELAXATION; CONNECTION;

D O I：

10.1080/15421406.2010.537869

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature-activated charge transport in disordered organic semiconductors at large carrier concentrations has been thoroughly considered, by using a recent analytical model [Phys.Rev.B 76, 045210 (2007)] assuming a Gaussian density-of-states (DOS) distribution and Miller-Abrahams jump rates. We demonstrate that the apparent Meyer-Neldel compensation rule is recovered with regard for the temperature dependences of the charge carrier mobility upon varying the carrier concentration, but not for varying the DOS distribution width. We show that this phenomenon is entirely due to the evolution of the occupational DOS distribution as a function of the state filling. Predictions of the model are in a quantitative agreement with available experimental results.

引用

页码：1 / 9

页数：9

共 26 条

[21] Temperature, electric-field, and carrier-density dependence of hopping magnetoresistivity in disordered organic semiconductors
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Liu, Ming
PHYSICAL REVIEW B, 2017, 96 (16)
[22] Unified description of charge-carrier mobilities in disordered organic semiconductors based on both Arrhenius and non-Arrhenius temperature dependence
L. G. Wang
H. W. Zhang
X. L. Tang
C. H. Mu
The European Physical Journal B, 2010, 74 : 1 - 7
[23] Unified description of charge-carrier mobilities in disordered organic semiconductors based on both Arrhenius and non-Arrhenius temperature dependence
Wang, L. G.
Zhang, H. W.
Tang, X. L.
Mu, C. H.
EUROPEAN PHYSICAL JOURNAL B, 2010, 74 (01): : 1 - 7
[24] Interplay between hopping and band transport in high-mobility disordered semiconductors at large carrier concentrations: The case of the amorphous oxide InGaZnO
Fishchuk, I. I.
Kadashchuk, A.
Bhoolokam, A.
de Meux, A. de Jamblinne
Pourtois, G.
Gavrilyuk, M. M.
Kohler, A.
Bassler, H.
Heremans, P.
Genoe, J.
PHYSICAL REVIEW B, 2016, 93 (19)
[25] CONCENTRATION-DEPENDENCE OF CHARGE-CARRIER MOBILITY IN DISORDERED ORGANIC MATRICES - COMPARISON OF A SMALL POLARON HOPPING MODEL WITH A DIPOLE TRAP MODEL
NOVIKOV, SV
VANNIKOV, AV
CHEMICAL PHYSICS LETTERS, 1994, 224 (5-6) : 501 - 507
[26] CONCENTRATION-DEPENDENCE OF CHARGE-CARRIER MOBILITY IN DISORDERED ORGANIC MATRICES - COMPARISON OF A MODEL OF SMALL RADIUS POLARITONS WITH DIPOLE TRAPS MODEL
NOVIKOV, SV
VANNIKOV, AV
KHIMICHESKAYA FIZIKA, 1994, 13 (8-9): : 47 - 53

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