Does the Temperature Dependence of the Charge Carrier Mobility in Disordered Organic Semiconductors at Large Carrier Concentrations Obey the Meyer-Neldel Compensation Law?

被引：6

作者：

Fishchuk, I. I. ^{[1
]}

Kadashchuk, A. K. ^{[2
,3
]}

Genoe, J. ^{[2
]}

Poroshin, V. N. ^{[3
]}

Baessler, H. ^{[4
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Nucl Res, Kiev, Ukraine

[2] IMEC, Heverlee, Belgium

[3] Natl Acad Sci Ukraine, Inst Phys, Kiev, Ukraine

[4] Univ Marburg, Marburg, Germany

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2011年 / 535卷 / 01期

关键词：

Charge carrier mobility; Gaussian density-of-states distribution; Mayer-Neldel rule; organic field-effect transistors; organic semiconductors; LIGHT-EMITTING-DIODES; RULE; TRANSPORT; TRANSISTORS; EXPLANATION; RELAXATION; CONNECTION;

D O I：

10.1080/15421406.2010.537869

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature-activated charge transport in disordered organic semiconductors at large carrier concentrations has been thoroughly considered, by using a recent analytical model [Phys.Rev.B 76, 045210 (2007)] assuming a Gaussian density-of-states (DOS) distribution and Miller-Abrahams jump rates. We demonstrate that the apparent Meyer-Neldel compensation rule is recovered with regard for the temperature dependences of the charge carrier mobility upon varying the carrier concentration, but not for varying the DOS distribution width. We show that this phenomenon is entirely due to the evolution of the occupational DOS distribution as a function of the state filling. Predictions of the model are in a quantitative agreement with available experimental results.

引用

页码：1 / 9

页数：9

共 26 条

[1] Temperature dependence of the charge carrier mobility in disordered organic semiconductors at large carrier concentrations
Fishchuk, I. I.
Kadashchuk, A. K.
Genoe, J.
Ullah, Mujeeb
Sitter, H.
Singh, Th. B.
Sariciftci, N. S.
Baessler, H.
PHYSICAL REVIEW B, 2010, 81 (04)
[2] Electric field dependence of charge-carrier hopping transport at large carrier concentrations in disordered organic solids: Meyer-Neldel and Gill energies
Fishchuk, I. I.
Kadashchuk, A.
Ullah, Mujeeb
Sitter, H.
Sariciftci, N. S.
Baessler, H.
14TH INTERNATIONAL CONFERENCE ON TRANSPORT IN INTERACTING DISORDERED SYSTEMS (TIDS-14), 2012, 376
[3] Origin of Meyer-Neldel type compensation behavior in organic semiconductors at large carrier concentrations: Disorder versus thermodynamic description
Fishchuk, I. I.
Kadashchuk, A.
Mityashin, A.
Gavrilyuk, M. M.
Koehler, A.
Baessler, H.
Genoe, J.
Sitter, H.
Sariciftci, N. S.
PHYSICAL REVIEW B, 2014, 90 (24)
[4] Origin of Meyer-Neldel type compensation behavior in organic semiconductors at large carrier concentrations: Disorder versus thermodynamic description (vol 90, 245201, 2014)
Fishchuk, I. I.
Kadashchuk, A.
Mityashin, A.
Gavrilyuk, M. M.
Koehler, A.
Baessler, H.
Genoe, J.
Sitter, H.
Sariciftci, N. S.
PHYSICAL REVIEW B, 2015, 91 (19):
[5] Charge carrier mobility in doped disordered organic semiconductors
Arkhipov, VI
Heremans, P
Emelianova, EV
Adriaenssens, GJ
Bässler, H
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2004, 338 : 603 - 606
[6] Parametrization of the charge-carrier mobility in organic disordered semiconductors
Baranovskii, S. D.
Nenashev, A. V.
Hertel, D.
Meerholz, K.
Gebhard, F.
PHYSICAL REVIEW APPLIED, 2024, 22 (01):
[7] Analytic model of hopping mobility at large charge carrier concentrations in disordered organic semiconductors:: Polarons versus bare charge carriers
Fishchuk, I. I.
Arkhipov, V. I.
Kadashchuk, A.
Heremans, P.
Baessler, H.
PHYSICAL REVIEW B, 2007, 76 (04)
[8] Charge Carriers Density, Temperature, and Electric Field Dependence of the Charge Carrier Mobility in Disordered Organic Semiconductors in Low Density Region
Shukri, Seyfan Kelil
Deja, Lemi Demeyu
CONDENSED MATTER, 2021, 6 (04):
[9] Carrier Density Dependence of the Mobility in Disordered Organic Semiconductors with Gaussian Disorder
Liang, Y. L.
Wang, L. G.
Wang, C. G.
Wang, G. C.
Zhang, L.
JOURNAL OF NANOELECTRONICS AND OPTOELECTRONICS, 2022, 17 (07) : 1098 - 1103
[10] Charge carrier mobility of disordered organic semiconductors with correlated energetic and spatial disorder
Kaiser, Waldemar
Albes, Tim
Gagliardi, Alessio
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (13) : 8897 - 8908

← 1 2 3 →