Synthesis and transformations of N-butyl-3(5)-nitro-1,2,4-triazoles under the conditions of acid-catalyzed alkylation of 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols

被引：0

作者：

Sukhanov, Gennady T. ^{[1
]}

Krupnova, Irina A. ^{[1
]}

Filippova, Yuliya, V ^{[1
]}

Gatilov, Yurii, V ^{[2
]}

Sukhanova, Anna G. ^{[1
]}

Bosov, Konstantin K. ^{[1
]}

Pivovarova, Ekaterina, V ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem & Energy Technol, Siberian Branch, 1 Sotsialisticheskaya St, Biisk 659322, Russia

[2] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, 9 Akad Lavrentieva Ave, Novosibirsk 630090, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2020年 / 56卷 / 11期

关键词：

1-(tert-butyl)-4-(sec-butyl)-3-nitro-1,2,4-triazolium salt; 1-(sec-butyl)-3,5-dinitro-1H-1,2,4-triazole; N-(sec-butyl)-3(5)-nitro-1,2,4-triazole; alkylation; isomers; transformation of alkyl substituent; X-ray structural analysis; 5-SUBSTITUTED TETRAZOLES; 3-NITRO-1,2,4-TRIAZOLE; ADAMANTYLAZOLES; 1,2,4-TRIAZOLE; DERIVATIVES;

D O I：

10.1007/s10593-020-02835-w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The directions of thermodynamically controlled rearrangements and transformations of alkyl substituents under the conditions of acidcatalyzed alkylation of unsubstituted and 5(3)-substituted 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols (n-, i-, tert-, sec-BuOH) were studied.

引用

页码：1440 / 1448

页数：9

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