Synthesis and transformations of N-butyl-3(5)-nitro-1,2,4-triazoles under the conditions of acid-catalyzed alkylation of 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols

被引：0
|
作者：
Sukhanov, Gennady T. [1 ]
Krupnova, Irina A. [1 ]
Filippova, Yuliya, V [1 ]
Gatilov, Yurii, V [2 ]
Sukhanova, Anna G. [1 ]
Bosov, Konstantin K. [1 ]
Pivovarova, Ekaterina, V [1 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem & Energy Technol, Siberian Branch, 1 Sotsialisticheskaya St, Biisk 659322, Russia
[2] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, 9 Akad Lavrentieva Ave, Novosibirsk 630090, Russia
来源：
CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2020年 / 56卷 / 11期
关键词：
1-(tert-butyl)-4-(sec-butyl)-3-nitro-1,2,4-triazolium salt; 1-(sec-butyl)-3,5-dinitro-1H-1,2,4-triazole; N-(sec-butyl)-3(5)-nitro-1,2,4-triazole; alkylation; isomers; transformation of alkyl substituent; X-ray structural analysis; 5-SUBSTITUTED TETRAZOLES; 3-NITRO-1,2,4-TRIAZOLE; ADAMANTYLAZOLES; 1,2,4-TRIAZOLE; DERIVATIVES;
D O I：
10.1007/s10593-020-02835-w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The directions of thermodynamically controlled rearrangements and transformations of alkyl substituents under the conditions of acidcatalyzed alkylation of unsubstituted and 5(3)-substituted 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols (n-, i-, tert-, sec-BuOH) were studied.
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收藏
页码：1440 / 1448
页数：9
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