Synthesis of new charge-compensated cobalt bis(1,2-dicarbollide) derivatives

被引：5

作者：

Kosenko, I. D. ^{[1
]}

Lobanova, I. A. ^{[1
]}

Starikova, Z. A. ^{[1
]}

Bregadze, V. I. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

cobalt bis(1,2-dicarbollide); charge-compensated derivatives; 8,8 '-mu-iodo-3-commo-3-cobalta-bis(1,2-dicarba-closo-dodecaborane); reactivity; X-ray diffraction studies; BIS(DICARBOLLIDE); DICARBOLLIDE; ION; 8,8'-MU-I-3,3'-CO(1,2-C2B9H10)(2); HYDROXYLATION; ACTIVATION; ZWITTERION; EXTRACTION; CHEMISTRY;

D O I：

10.1007/s11172-013-0275-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New hetero-substituted charge-compensated cobalt bis(1,2-dicarbollide) derivatives were synthesized by the reaction of 8,8'-mu-iodo-3-commo-3-cobalta-bis(1,2-dicarba-closo-dodecaborane) [8,8'-mu-I-3,3'-Co(1,2-C2B9H10)(2)] with 1,4-thioxane, pyridine N-oxide, and tetrahydropyran. X-ray diffraction studies showed that the 8'-iodo-8-(pyridiniumoxy)eucosahydro-1,1',2,2'-tetracarba-3-commo-cobalta-closo-tricosaborate molecule has the gauche-conformation (the substituents are turned with respect to each other by 69.2A degrees). The positive charge is predominantly localized on the N(Py) atom.

引用

页码：1914 / 1918

页数：5

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