Effects of Wheat Straw Fiber Content and Characteristics, and Coupling Agent Concentration on the Mechanical Properties of Wheat Straw Fiber-Polypropylene Composites

被引:19
|
作者
Pan, Ming-Zhu [1 ,2 ,3 ]
Zhou, Ding-Guo [2 ]
Bousmina, Mosto [3 ]
Zhang, S. Y. [1 ]
机构
[1] Fpinnovat Forintek Div, Vancouver, BC V6T 1W5, Canada
[2] Nanjing Forestry Univ, Coll Wood Sci & Technol, Nanjing 210037, Peoples R China
[3] Univ Laval, Dept Chem Engn, Quebec City, PQ G1K 7P4, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
composites; fibers; mechanical properties; morphology; poly(propylene) (PP); TENSILE PROPERTIES;
D O I
10.1002/app.29789
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Wheat straw fiber-polypropylene (PP) composites were prepared to investigate the effects of wheat straw fiber content (10, 20, 30, 40, and 50 wt %), fiber size (9, 28, and 35 mesh), and maleic anhydride grafted polypropylene (MAPP) concentration (1, 2, 5, and 10 wt %) on the static and dynamic mechanical properties of the wheat straw fiber-PP composites in this study. The tensile modulus and strength of the composites increased linearly with increasing wheat straw fiber content up to 40%, whereas the elongation at break decreased dramatically to 3.78%. Compared with the composites made of the longer wheat straw fiber, the composites made of the fines (>35 mesh) had a slightly higher tensile strength of 31.2 MPa and tensile elongation of 5.39% at break. With increasing MAPP concentration, the composites showed an increase in tensile strength, and the highest tensile strength of 34.0 MPa occurred when the MAPP concentration reached 10 wt %. As wheat straw fiber content increased from 0 to 40%, the flexural modulus of the composites increased gradually from 1335 to 3437 MPa. The MAPP concentration and wheat straw fiber size distribution had no appreciable effect on the static flexural modulus of the composites. The storage flexural modulus of the composites increased with increasing wheat straw fiber content. The scanning electron microscopy (SEM) observation on the fracture surface of the composites indicated that a high wheat straw fiber content (>30 wt %) resulted in fiber agglomeration and a reduction in interfacial bonding strength. (C) 2009 Wiley Periodicals, fnc. J Appl Polym Sci 113: 1000-1007, 2009
引用
收藏
页码:1000 / 1007
页数:8
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