Approach to pactamycin analogues using rhodium(II)-catalyzed alkene aziridination and C(sp3)-H amination reactions

被引：8

作者：

Rodrigues, Romain ^{[1
]}

Lazib, Yanis ^{[1
]}

Maury, Julien ^{[1
,2
]}

Neuville, Luc ^{[1
]}

Leboeuf, David ^{[2
]}

Dauban, Philippe ^{[1
]}

Darses, Benjamin ^{[1
]}

机构：

[1] Univ Paris Saclay, Univ Paris Sud, Inst Chim Subst Nat, CNRS,UPR 2301, 1 Ave Terrasse, F-91198 Gif Sur Yvette, France

[2] Univ Paris Saclay, Univ Paris Sud, Inst Chim Mol & Mat Orsay, CNRS,UMR 8182, Batiment 420, F-91405 Orsay, France

来源：

ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 06期

关键词：

C-H AMINATION; COPPER-CATALYZED AZIRIDINATION; 30S RIBOSOMAL-SUBUNIT; HIGHLY EFFICIENT; CORE FRAMEWORK; ANTITUMOR; BONDS; CYCLOPENTANE; CONSTRUCTION; ANTIBIOTICS;

D O I：

10.1039/c7qo00878c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dirhodium(ii)-catalyzed nitrene transfers have been used to prepare a novel synthetic platform bearing the triamino moiety present in pactamycin, jogyamycin and cranomycin. Catalytic intramolecular C(sp(3))-H amination and alkene aziridination reactions, the latter followed by a nucleophilic aziridine ring opening, are the key steps of this strategy.

引用

页码：948 / 953

页数：6

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