Approach to pactamycin analogues using rhodium(II)-catalyzed alkene aziridination and C(sp3)-H amination reactions

被引：8
|
作者：
Rodrigues, Romain [1 ]
Lazib, Yanis [1 ]
Maury, Julien [1 ,2 ]
Neuville, Luc [1 ]
Leboeuf, David [2 ]
Dauban, Philippe [1 ]
Darses, Benjamin [1 ]
机构：
[1] Univ Paris Saclay, Univ Paris Sud, Inst Chim Subst Nat, CNRS,UPR 2301, 1 Ave Terrasse, F-91198 Gif Sur Yvette, France
[2] Univ Paris Saclay, Univ Paris Sud, Inst Chim Mol & Mat Orsay, CNRS,UMR 8182, Batiment 420, F-91405 Orsay, France
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 06期
关键词：
C-H AMINATION; COPPER-CATALYZED AZIRIDINATION; 30S RIBOSOMAL-SUBUNIT; HIGHLY EFFICIENT; CORE FRAMEWORK; ANTITUMOR; BONDS; CYCLOPENTANE; CONSTRUCTION; ANTIBIOTICS;
D O I：
10.1039/c7qo00878c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Dirhodium(ii)-catalyzed nitrene transfers have been used to prepare a novel synthetic platform bearing the triamino moiety present in pactamycin, jogyamycin and cranomycin. Catalytic intramolecular C(sp(3))-H amination and alkene aziridination reactions, the latter followed by a nucleophilic aziridine ring opening, are the key steps of this strategy.
引用
收藏
页码：948 / 953
页数：6
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