Chiral sulfoxides and sulfides tethered to pyridines as ligands for enantioselective catalysis: Palladium catalyzed allylic substitution and addition of diethylzinc to benzaldehyde

被引:68
|
作者
Chelucci, G
Berta, D
Saba, A
机构
[1] Dipartimento di Chimica, Universita' di Sassari, I-07100 Sassari
关键词
D O I
10.1016/S0040-4020(97)00113-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chiral 2-(1-p-tolylsulfinyl)alkylpyridines and the corresponding sulfide-pyridines were prepared and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethylmalonate and addition of diethylzinc to benzaldehyde. (C) 1997 Published by Elsevier Science Ltd.
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页码:3843 / 3848
页数:6
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