Electrospinning and Microwave Absorption of Polyaniline/Polyacrylonitrile/Multiwalled Carbon Nanotubes Nanocomposite Fibers

被引:44
|
作者
Zhang, Zhichun [1 ]
Zhang, Fenghua [1 ]
Jiang, Xueyong [1 ]
Liu, Yanju [2 ]
Guo, Zhanhu [3 ]
Leng, Jinsong [1 ]
机构
[1] Harbin Inst Technol, Ctr Composite Mat & Struct, Harbin 150080, Peoples R China
[2] Harbin Inst Technol, Dept Astronaut Sci & Mech, Harbin 150001, Peoples R China
[3] Lamar Univ, Dan F Smith Dept Chem Engn, Integrated Composites Lab, Beaumont, TX 77710 USA
基金
中国国家自然科学基金;
关键词
Fibers; Nano-structures; Polymer-matrix composites; Electrical properties; POLYACRYLONITRILE NANOFIBERS; FABRICATION; MEMBRANES; NANOPARTICLES; ACID; POLYMERIZATION; CONDUCTIVITY; GENERATION; PROPERTY; ROUTE;
D O I
10.1007/s12221-014-2290-5
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
Electrical conductive nanocomposite fibers were prepared with polyaniline (PANI), polyacrylonitrile (PAN) and multi-walled carbon nanotubes (MWCNTs) via electrospinning. The morphology and electrical conductivity of the PANI/PAN/MWCNTs nanocomposite fibers were characterized by scanning electron microscope (SEM) and Van De Pauw method. Electrical conductivity of nanocomposite fibers increased from 1.79 S.m(-1) to 7.97 S.m(-1) with increasing the MWCNTs content from 3.0 wt% to 7.0 wt%. Compared with PANI/PAN membranes, the mechanical property of PANI/PAN/MWCNTs nanocomposites fiber membranes decreased. The microwave absorption performance of composite films was analyzed using waveguide tube, which indicated that with the thickness increasing the value of R-L reduced from -4.6 to -5.9 dB.
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页码:2290 / 2296
页数:7
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