Preparation, structures, and properties of nickel complexes containing 2,6-bis[4', 4'-dimethyloxazolin-2'-yl] pyridine, a pincer ligand

被引：5

作者：

Jia, Wei-Guo ^{[1
]}

Li, Dan-Dan ^{[1
]}

Yan, Li-Qin ^{[1
]}

Sheng, En-Hong ^{[1
]}

Dai, Yuan-Chen ^{[1
]}

机构：

[1] Anhui Normal Univ, Coll Chem & Mat Sci, Ctr Nano Sci & Technol,Minist Educ, Anhui Lab Mol Based Mat,Key Lab Funct Mol So, Wuhu, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 67卷 / 02期

关键词：

Pincer; Nickel; Synthesis; Structure; Non-covalent interactions; CENTER-DOT-X; HYDROSILYLATION; KETONES;

D O I：

10.1080/00958972.2014.886109

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five- and six-coordinate nickel complexes [(Dm-Pybox)NiCl2], [(Dm-Pybox)Ni(H2O)Cl-2], [(Dm-Pybox)Ni(H2O)(2)Cl]Cl (2a), and [(Dm-Pybox)Ni(MeOH)(2)Cl]Cl (2b), where Dm-Pybox is 2,6-bis[4,4-dimethyloxazolin-2-yl]pyridine, have been isolated and structurally characterized by single crystal X-ray diffraction. The solid state structures of 2a and 2b feature different modes of non-covalent interactions, C-HCl, C-HO and O-HCl interactions. Spectroscopic and analytical methods, UV-vis and thermogravimetric analyses were done to further investigate chemical properties of the complexes.

引用

页码：363 / 371

页数：9

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