Preparation, structures, and properties of nickel complexes containing 2,6-bis[4', 4'-dimethyloxazolin-2'-yl] pyridine, a pincer ligand

被引：5
|
作者：
Jia, Wei-Guo [1 ]
Li, Dan-Dan [1 ]
Yan, Li-Qin [1 ]
Sheng, En-Hong [1 ]
Dai, Yuan-Chen [1 ]
机构：
[1] Anhui Normal Univ, Coll Chem & Mat Sci, Ctr Nano Sci & Technol,Minist Educ, Anhui Lab Mol Based Mat,Key Lab Funct Mol So, Wuhu, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 67卷 / 02期
关键词：
Pincer; Nickel; Synthesis; Structure; Non-covalent interactions; CENTER-DOT-X; HYDROSILYLATION; KETONES;
D O I：
10.1080/00958972.2014.886109
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Five- and six-coordinate nickel complexes [(Dm-Pybox)NiCl2], [(Dm-Pybox)Ni(H2O)Cl-2], [(Dm-Pybox)Ni(H2O)(2)Cl]Cl (2a), and [(Dm-Pybox)Ni(MeOH)(2)Cl]Cl (2b), where Dm-Pybox is 2,6-bis[4,4-dimethyloxazolin-2-yl]pyridine, have been isolated and structurally characterized by single crystal X-ray diffraction. The solid state structures of 2a and 2b feature different modes of non-covalent interactions, C-HCl, C-HO and O-HCl interactions. Spectroscopic and analytical methods, UV-vis and thermogravimetric analyses were done to further investigate chemical properties of the complexes.
引用
收藏
页码：363 / 371
页数：9
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