Imido analogues of p-block oxoanions

被引:45
|
作者
Aspinall, GM [1 ]
Copsey, MC [1 ]
Leedham, AP [1 ]
Russell, CA [1 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
基金
英国工程与自然科学研究理事会;
关键词
main groups; imido; anions; lithium;
D O I
10.1016/S0010-8545(02)00014-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of imido analogues of p-block oxoanions is a relatively new area of investigation. This review summarises synthetic routes towards such anions and gives an analysis of the structure and reactivity of complexes containing the following anions, [B(NR)(3)](3-) : [C(NR)(3)](2-): [Si(NR)(4)](4-); [P(NR)(4)](3-) [HP(NR)(3)](2-): [As(NR)(3)](3-) [Sb(NR)(3)](3-) [S(NR)(3)](2-): [Se(NR)(3)](2-) [Te(NR)(3)](2-) and [S(NR)(4)](2-). (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:217 / 232
页数:16
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