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Imido analogues of p-block oxoanions
被引:45
|作者:
Aspinall, GM
[1
]
Copsey, MC
[1
]
Leedham, AP
[1
]
Russell, CA
[1
]
机构:
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
基金:
英国工程与自然科学研究理事会;
关键词:
main groups;
imido;
anions;
lithium;
D O I:
10.1016/S0010-8545(02)00014-0
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
The synthesis of imido analogues of p-block oxoanions is a relatively new area of investigation. This review summarises synthetic routes towards such anions and gives an analysis of the structure and reactivity of complexes containing the following anions, [B(NR)(3)](3-) : [C(NR)(3)](2-): [Si(NR)(4)](4-); [P(NR)(4)](3-) [HP(NR)(3)](2-): [As(NR)(3)](3-) [Sb(NR)(3)](3-) [S(NR)(3)](2-): [Se(NR)(3)](2-) [Te(NR)(3)](2-) and [S(NR)(4)](2-). (C) 2002 Elsevier Science B.V. All rights reserved.
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页码:217 / 232
页数:16
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