3,3,6,6-tetrarnethyl-1,2,4,5-tetroxane:: a twinned crystal structure

被引:12
|
作者
Gelalcha, FG
Schulze, B
Lönnecke, P
机构
[1] Univ Leipzig, Inst Organ Chem, D-04103 Leipzig, Germany
[2] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany
关键词
D O I
10.1107/S010827010400112X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C6H12O4, also known as dimeric acetone peroxide, Me-2(C2O4)Me-2, has crystallographically imposed inversion symmetry and adopts a chair conformation in the solid state. This structure contrasts with that of the sulfur homologue Me-2(C2S4)Me-2, which has crystallographically imposed (4) over bar symmetry and crystallizes in a twist-boat conformation. Crystals of the title compound are twinned along the reciprocal c* axis.
引用
收藏
页码:O180 / O182
页数:3
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