3,3,6,6-tetrarnethyl-1,2,4,5-tetroxane:: a twinned crystal structure

被引：12
|
作者：
Gelalcha, FG
Schulze, B
Lönnecke, P
机构：
[1] Univ Leipzig, Inst Organ Chem, D-04103 Leipzig, Germany
[2] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷
关键词：
D O I：
10.1107/S010827010400112X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, C6H12O4, also known as dimeric acetone peroxide, Me-2(C2O4)Me-2, has crystallographically imposed inversion symmetry and adopts a chair conformation in the solid state. This structure contrasts with that of the sulfur homologue Me-2(C2S4)Me-2, which has crystallographically imposed (4) over bar symmetry and crystallizes in a twist-boat conformation. Crystals of the title compound are twinned along the reciprocal c* axis.
引用
收藏
页码：O180 / O182
页数：3
相关论文
共 50 条
  • [1] Gas-phase structure and conformational properties of 3,3,6,6-tetramethyl-1,2,4,5-tetroxane
    Shlykov, Sergey A.
    Giricheva, Nina I.
    Eyler, Gladys N.
    Oberhammer, Heinz
    JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (07): : 1368 - 1373
  • [2] Experimental and theoretical studies of the vibrational spectra of 3,3,6,6-tetramethyl-1,2,4,5-tetroxane
    Jubert, AH
    Diez, RP
    Cafferata, LFR
    JOURNAL OF RAMAN SPECTROSCOPY, 1999, 30 (06) : 479 - 484
  • [3] THERMAL DECOMPOSITION REACTION OF 3,3,6,6-TETRAMETHYL-1,2,4,5-TETROXANE IN 2-METHOXYETHANOL SOLUTION
    Leiva, L. A. C.
    Romero, J. M.
    Jorge, N. L.
    Cafferata, L. F. R.
    Gomez Vara, M. E.
    Castro, E. A.
    CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2009, 45 (12) : 1455 - 1459
  • [4] Thermal decomposition reaction of 3,3,6,6-tetramethyl- 1,2,4,5-tetroxane in 2-methoxy- ethanol solution
    L. A. C. Leiva
    J. M. Romero
    N. L. Jorge
    L. F. R. Cafferata
    M. E. Gómez Vara
    E. A. Castro
    Chemistry of Heterocyclic Compounds, 2009, 45 : 1455 - 1459
  • [5] A conformational study of 3,3,6,6-tetramethyl-1,2,4,5-tetroxane using molecular dynamics and density functional theory
    Diez, RP
    Jubert, AH
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2000, 499 : 85 - 89
  • [6] Structural stability and analysis of vibrational spectra of 1,2,4,5-tetroxane and 3,6-diphenyl-1,2,4,5-tetroxane
    Badawi, H. M.
    Al-Saadi, A. A.
    Ali, S. A.
    JOURNAL OF MOLECULAR STRUCTURE, 2010, 969 (1-3) : 197 - 203
  • [7] A vibrational study of 3,3,6,6-tetramethyl-1,2,4,5-tetroxane: The spectra of the deuterated substance and the scaled quantum mechanics force field
    Coronel, A. C.
    Agueera, M. B.
    Torres, A. C.
    Fernandez, L. E.
    Varetti, E. L.
    VIBRATIONAL SPECTROSCOPY, 2012, 58 : 67 - 73
  • [8] Conformational analysis of 1,2,4,5-tetroxane
    Jorge, N
    Gómez-Vara, M
    Romero, JR
    Castro, EA
    BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 2002, 50 (03): : 387 - 395
  • [9] Structural and spectroscopic study of 3,6-dibutanoic-1,2,4,5-tetroxane
    Romero, JM
    Profeta, MI
    Jorge, NL
    Gómez-Vara, ME
    Castro, EA
    Jubert, AH
    MOLECULAR SIMULATION, 2005, 31 (14-15) : 1075 - 1081
  • [10] Theoretical study of the gas-phase thermolysis of 3-methyl-1,2,4,5-tetroxane
    Mariela Inés Profeta
    Jorge Marcelo Romero
    Nelly Lidia Jorge
    André Grand
    Alfonso Hernández-Laguna
    Journal of Molecular Modeling, 2014, 20
12345