Diorganosilicon(IV) complexes of heterocyclic dithiocarbamates. Synthesis and structural elucidations

被引：0

作者：

Sharma, J ^{[1
]}

Singh, YP ^{[1
]}

Rai, AK ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

MAIN GROUP METAL CHEMISTRY | 1999年 / 22卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diorganosilicon(IV) complexes of heterocyclic dithiocarbamates having general formula [CH2CH2(X)CH2CH2NCS2](2)SiR2 (where R = CH3, X = CH2, CH-CH3 and R = C6H5, X = CH2, CH-CH3, O) have been synthesized by the interaction of diorganodichlorosilicon with the sodium salt of heterocyclic dithiocarbamates in a 1 : 2 stoichiometric ratio. The resulting complexes were characterized by elemental analysis, molecular weight measurements and a tetracoordinated geometry around silicon atom has been proposed on the basis of IR and. NMR (H-1, C-13 and Si-29) spectral studies.

引用

页码：595 / 598

页数：4

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