A novel method of calculating the interaction energies of double layers

被引:0
|
作者
Zhang, Shimin [1 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
关键词
lambda parameter method; double layer; interaction energies; elliptical integral;
D O I
10.1142/S0218625X06007780
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel, simple, and efficient method to calculate the interaction energies of double layers, lambda parameter method, is presented by introducing a parameter lambda in the elliptical integral. The interaction energies between two similar plane parallel double layers are expanded in the power series with such a method. The series converge very fast. When the dimensionless surface potential of double layers is less than or equal to 30, the number of the series terms required does not exceed 3 to obtain the interaction energies with six significant digits.
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页码:127 / 133
页数:7
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