The application of the λ parameter method to calculation of the interaction energies between two plane parallel double layers for symmetric electrolytes

被引:2
|
作者
Zhang, Shimin [1 ]
Zhang, Shizhuo [2 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha, Hunan, Peoples R China
[2] Kansas State Univ, Dept Math, Manhattan, KS 66506 USA
关键词
RAPIDLY CONVERGENT SERIES; ASYMMETRIC ELECTROLYTES;
D O I
10.1134/S1061933X09060064
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The lambda parameter method had successfully been applied to calculate the interaction energies between two plane parallel double layers for symmetric electrolytes. When y(0) and |y(d)|<= 20, the number of the series terms required to obtain the interaction energies with six significant digits is not more than 4. If we regard the interaction energies as the function of the hyperbolic function tanh (y(0)/2) instead of tanh(y(0)/4), then calculating it with the aid of lambda parameter method, we can obtain above results at once. This enables one to avoid the mathematical complexity of other methods.
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页码:771 / 783
页数:13
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