Triphenylphosphine dibromide: A useful reagent for conversion of aldoximes into nitriles

被引：4

作者：

Darvish, Fatemeh ^{[1
]}

Movassagh, Barahman ^{[1
]}

Erfani, Masoud ^{[1
]}

机构：

[1] KN Toosi Univ Technol, Dept Chem, Tehran, Iran

来源：

ARABIAN JOURNAL OF CHEMISTRY | 2015年 / 8卷 / 06期

关键词：

Aldoxime; Nitrile; Dehydration; Triphenylphosphine dibromide; EFFICIENT BECKMANN REARRANGEMENT; DEHYDRATION;

D O I：

10.1016/j.arabjc.2012.09.008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and convenient method for the synthesis of nitriles by dehydration of aldoximes has been developed using triphenylphosphine dibromide in acetonitrile at room temperature. A variety of aromatic and heteroaromatic aldoximes are converted into the corresponding nitriles in high yields. (C) 2012 Production and hosting by Elsevier B.V. on behalf of King Saud University.

引用

页码：865 / 867

页数：3

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