Self-Assembly of Silver(I) Coordination Polymers Formed through Hydrogen Bonding with Ditopic Heteroscorpionate Ligands

被引：20

作者：

Santillan, Guillermo A. ^{[1
]}

Carrano, Carl J. ^{[1
]}

机构：

[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 03期

关键词：

MOLECULAR TRIANGLE; BIS(PYRAZOLYL)METHANE LIGANDS; SUPRAMOLECULAR ISOMERISM; COMPLEXES; DESIGN; CONSTRUCTION; GEOMETRY; NETWORK; ANION; METALLACYCLES;

D O I：

10.1021/cg801256h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Eight coordination polymers of silver Ag(l) derived from bidentate coordinating heteroscorpionate ligands, (4-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L4c) and (3-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L3c), have been synthesized and characterized by X-ray diffraction, ESI-MS, IR spectroscopy, and elemental analysis. By varying the solvent polarity, the protonation state of the uncoordinated carboxylate groups and hence their solid-state interactions can be controlled. While the silver monomers (tectons) possess chirality due to the asymmetric coordination of the achiral ligands to the silver ion, all of the solid-state materials were isolated as racemic mixtures.

引用

页码：1590 / 1598

页数：9

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