Self-Assembly of Silver(I) Coordination Polymers Formed through Hydrogen Bonding with Ditopic Heteroscorpionate Ligands

被引：20
|
作者：
Santillan, Guillermo A. [1 ]
Carrano, Carl J. [1 ]
机构：
[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA
来源：
CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 03期
关键词：
MOLECULAR TRIANGLE; BIS(PYRAZOLYL)METHANE LIGANDS; SUPRAMOLECULAR ISOMERISM; COMPLEXES; DESIGN; CONSTRUCTION; GEOMETRY; NETWORK; ANION; METALLACYCLES;
D O I：
10.1021/cg801256h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Eight coordination polymers of silver Ag(l) derived from bidentate coordinating heteroscorpionate ligands, (4-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L4c) and (3-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L3c), have been synthesized and characterized by X-ray diffraction, ESI-MS, IR spectroscopy, and elemental analysis. By varying the solvent polarity, the protonation state of the uncoordinated carboxylate groups and hence their solid-state interactions can be controlled. While the silver monomers (tectons) possess chirality due to the asymmetric coordination of the achiral ligands to the silver ion, all of the solid-state materials were isolated as racemic mixtures.
引用
收藏
页码：1590 / 1598
页数：9
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