MEAN DROP SIZE;
ENERGY-DISSIPATION;
EMULSIFICATION;
COALESCENCE;
HOMOGENIZER;
TURBULENCE;
BREAKUP;
FLOW;
D O I:
10.1021/acs.iecr.9b00634
中图分类号:
TQ [化学工业];
学科分类号:
0817 ;
摘要:
This work reports for the first time on the use of Confined Impinging Jet Mixers (CIJM) for the production of emulsions with dispersed-phase content up to 80 wt %, in both the surfactant-poor and -rich regimes, following the exposure to varying CIJM hydrodynamic conditions. It was observed computationally and experimentally that the CIJM capacity resulted strictly dependent on the mass jet flow rate (W-jet > 176 g/min) and the pre-emulsion droplet size (>10 mu m). CIJM emulsification performance remained (almost) unaffected by the variation in the oil mass fraction. All systems showed the lowest droplet size (similar to 8 mu m) and similar droplet size distributions under the highest W-jet. Conditionally onto the Tween20 availability, the emulsion d(3)(,2) was primarily determined by formulation characteristics in the surfactant poor-regime and by the CIJM energy dissipation rate in the surfactant-rich regime. In conclusion, this study offers further insights into the CIJM suitability as a realistic alternative to already-established emulsification methods.
机构:
Tokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, JapanTokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
Motoyama, Takumi
Katsuumi, Yuka
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机构:
Tokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, JapanTokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
Katsuumi, Yuka
Sasakura, Hiromu
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机构:
T HASEGAWA CO LTD, Nakahara Ku, Kariyado 29-7, Kawasaki, Kanagawa 2110022, JapanTokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
Sasakura, Hiromu
Nakamura, Tetsuya
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机构:
T HASEGAWA CO LTD, Nakahara Ku, Kariyado 29-7, Kawasaki, Kanagawa 2110022, JapanTokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
Nakamura, Tetsuya
Suzuki, Hisashi
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机构:
T HASEGAWA CO LTD, Nakahara Ku, Kariyado 29-7, Kawasaki, Kanagawa 2110022, JapanTokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
Suzuki, Hisashi
Tsuchiya, Koji
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机构:
Tokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, JapanTokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
Tsuchiya, Koji
Akamatsu, Masaaki
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机构:
Tokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, JapanTokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
Akamatsu, Masaaki
Sakai, Kenichi
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机构:
Tokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
Tokyo Univ Sci, Res Inst Sci & Technol, 2641 Yamazaki, Noda, Chiba 2788510, JapanTokyo Univ Sci, Fac Sci & Technol, Dept Pure & Appl Chem, 2641 Yamazaki, Noda, Chiba 2788510, Japan
机构:
Department of Chemical Engineering, University of Waterloo, Waterloo, Ont. N2L 3G1, CanadaDepartment of Chemical Engineering, University of Waterloo, Waterloo, Ont. N2L 3G1, Canada
Buhidma, A.
Pal, R.
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机构:
Department of Chemical Engineering, University of Waterloo, Waterloo, Ont. N2L 3G1, CanadaDepartment of Chemical Engineering, University of Waterloo, Waterloo, Ont. N2L 3G1, Canada