Ring-closing metathesis for the synthesis of a molecular gyrotop

被引：27

作者：

Setaka, Wataru ^{[1
]}

Higa, Sayaka ^{[2
]}

Yamaguchi, Kentaro ^{[2
]}

机构：

[1] Tokyo Metropolitan Univ, Fac Urban Environm Sci, Div Appl Chem, Hachioji, Tokyo 1920397, Japan

[2] Tokushima Bunri Univ, Fac Pharmaceut Sci, Sanuki, Kagawa 7692193, Japan

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2014年 / 12卷 / 21期

关键词：

GYROSCOPE-LIKE MOLECULES; 3-SPOKE STATORS; PALLADIUM COMPLEXES; PHENYLENE ROTATOR; CATALYSTS; DYNAMICS; CAGE; MACHINES; PLATINUM; LIGANDS;

D O I：

10.1039/c4ob00470a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Macrocage molecules with a bridged phenylene rotor have been synthesized as molecular gyrotops, whose cages were constructed by ring-closing metathesis (RCM) of bis(trialkenylsilyl) benzenes. An analysis of the yields of the products in the RCM reaction under various temperature conditions revealed that the desired cage, i.e., a molecular gyrotop, was produced in good yield under reflux, indicating that the cage is a thermodynamically controlled product.

引用

页码：3354 / 3357

页数：4

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