Synthesis and alkali cation extraction ability of 1,3-alt-thiacalix[4]mono(crown) ethers

被引：42
|
作者：
Csokai, V
Grün, A
Parlagh, G
Bitter, I [1 ]
机构：
[1] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1521 Budapest, Hungary
[2] Budapest Univ Technol & Econ, Dept Phys Chem, H-1521 Budapest, Hungary
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 42期
基金：
匈牙利科学研究基金会;
关键词：
thiacalix[4]arenes; crown ether bridge; complexation; alkali cations;
D O I：
10.1016/S0040-4039(02)01594-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first representatives of 1,3-alt-thiacalix[4]mono(crown-5 and -6) ethers were synthesized by the cyclocondensation of 25,27-dialkoxythiacalix[4]arenes with tetraethylene glycol ditosylate and 1,14-diiodo-3,6,9,12-tetraoxatetradecane, respectively. The complexing abilities of ligands were determined by the alkali (Li+, Na+, K+, Rb+, Cs+) picrate extraction method. (C) 2002 Elsevier Science Ltd. All rights reserved.
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收藏
页码：7627 / 7629
页数：3
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