Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

被引：8
|
作者：
Mishima, Akio [1 ]
Koshiyama, Tomomi [1 ]
Real, Jose A. [2 ]
Ohba, Masaaki [1 ]
机构：
[1] Kyushu Univ, Grad Sch Sci, Dept Chem, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
[2] Univ Valencia, Inst Ciencia Mol ICMol, Paterna 46980, Spain
来源：
JOURNAL OF MATERIALS CHEMISTRY C | 2017年 / 5卷 / 15期
关键词：
METAL-ORGANIC FRAMEWORKS; SPIN-CROSSOVER COMPOUND; ROOM-TEMPERATURE; NANOCRYSTALLINE MATERIALS; TRANSITION-TEMPERATURE; PROTON CONDUCTION; HYDROGEN STORAGE; NANOPARTICLES; BISTABILITY; ADSORPTION;
D O I：
10.1039/c7tc00751e
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)(4)]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.
引用
收藏
页码：3706 / 3713
页数：8
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