How to overcome Coulomb explosions in labile dications by using the [B12Cl12]2- dianion

被引：35

作者：

Knapp, Carsten ^{[1
]}

Schulz, Christoph ^{[1
]}

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg I Br, Germany

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 33期

关键词：

CRYSTAL-STRUCTURE; COMPLEXES; SO2;

D O I：

10.1039/b908970e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dicationic homoleptic lithium-sulfur dioxide complex [Li-2(SO2)(8)](2+) in [Li-2(SO2)(8)][B12Cl12] has been characterized by X-ray diffraction; [Li-2(SO2)(8)](2+) is stabilized in the solid state by the weakly-coordinating dianion[B12Cl12](2-) and the high lattice enthalpy of the resulting dication-dianion salt.

引用

页码：4991 / 4993

页数：3

共 44 条

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