How to overcome Coulomb explosions in labile dications by using the [B12Cl12]2- dianion

被引：35
|
作者：
Knapp, Carsten [1 ]
Schulz, Christoph [1 ]
机构：
[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg I Br, Germany
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 33期
关键词：
CRYSTAL-STRUCTURE; COMPLEXES; SO2;
D O I：
10.1039/b908970e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dicationic homoleptic lithium-sulfur dioxide complex [Li-2(SO2)(8)](2+) in [Li-2(SO2)(8)][B12Cl12] has been characterized by X-ray diffraction; [Li-2(SO2)(8)](2+) is stabilized in the solid state by the weakly-coordinating dianion[B12Cl12](2-) and the high lattice enthalpy of the resulting dication-dianion salt.
引用
收藏
页码：4991 / 4993
页数：3
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