The effect of heterogeneous acid-base catalysis on conversion of 5-hydroxymethylfurfural into a cyclopentanone derivative

被引：73
|
作者：
Ohyama, J. [1 ,2 ]
Kanao, R. [1 ]
Ohira, Y. [1 ]
Satsuma, A. [1 ,2 ]
机构：
[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Nagoya, Aichi 4648603, Japan
[2] Kyoto Univ, Elements Strategy Initiat Catalysts & Batteries E, Kyoto 6068501, Japan
来源：
GREEN CHEMISTRY | 2016年 / 18卷 / 03期
关键词：
SELECTIVE CONVERSION; RING REARRANGEMENT; BIOMASS; TRANSFORMATION; HYDROGENATION; CHEMICALS; FUELS;
D O I：
10.1039/c5gc01723h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effect of heterogeneous acid-base catalysis on conversion of 5-hydroxymethylfurfural (HMF) to 3-hydroxymethylcyclo-pentanone (HCPN) was investigated. It was demonstrated that acidic metal oxides, in particular Ta2O5, significantly enhanced the yield of HCPN due to their moderate Lewis acidity.
引用
收藏
页码：676 / 680
页数：5
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