Strong basic sites accelerate the deactivation of oxide catalysts supported on FSM-16 for the vapor-phase Beckmann rearrangement of cyclohexanone oxime

被引：2
|
作者：
Shouro, D [1 ]
Nakajima, T [1 ]
Mishima, S [1 ]
机构：
[1] Shinshu Univ, Fac Engn, Dept Chem & Mat Engn, Nagano 3808553, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 12期
关键词：
D O I：
10.1246/cl.1999.1319
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The acidic and basic properties of FSM-16-supported Al2O3, ZnO or CdO were determined by the temperature-programmed desorption (TPD) of ethylamine. Relationship of the deactivation rate of the catalyst during the vapor-phase Beckmann rearrangement with the acidic and basic properties was studied. It was found that the deactivation was accelerated with an increase in the amount of the strong basic sites.
引用
收藏
页码：1319 / 1320
页数：2
相关论文
共 50 条
  • [31] A quantum chemical study of vapor-phase Beckmann rearrangement mechanisms on oxide catalysts
    Shinohara, Y
    Mae, S
    Shouro, D
    Nakajima, T
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2000, 497 : 1 - 9
  • [32] VAPOR-PHASE BECKMANN REARRANGEMENT OF CYCLOHEXANONE OXIME OVER AN HY ZEOLITE CATALYST CALCINED AT HIGH-TEMPERATURE
    SATO, S
    TAKEMATSU, K
    SODESAWA, T
    NOZAKI, F
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (06) : 1486 - 1490
  • [33] Deactivation and regeneration of B2O3/TiO2-ZrO2 catalyst for vapor-phase Beckmann rearrangement of cyclohexanone oxime
    Mao, DS
    Lu, GZ
    Chen, QL
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2003, 19 (04) : 381 - 386
  • [34] VAPOR-PHASE BECKMANN REARRANGEMENT OF CYCLOHEXANONE OXIME OVER SILICA BORIA CATALYST PREPARED BY CHEMICAL VAPOR-DEPOSITION METHOD
    SATO, S
    SAKURAI, H
    URABE, K
    IZUMI, Y
    CHEMISTRY LETTERS, 1985, (03) : 277 - 278
  • [35] Mesoporous molecular sieve Al-MCM-41 as a novel catalyst for vapor-phase Beckmann rearrangement of cyclohexanone oxime
    An-Nan. Ko
    Chia-Chun Hung
    Chih-Wei Chen
    Kuang-Hao Ouyang
    Catalysis Letters, 2001, 71 : 219 - 224
  • [36] Mesoporous molecular sieve Al-MCM-41 as a novel catalyst for vapor-phase Beckmann rearrangement of cyclohexanone oxime
    Ko, AN
    Hung, CC
    Chen, CW
    Ouyang, KH
    CATALYSIS LETTERS, 2001, 71 (3-4) : 219 - 224
  • [37] VAPOR-PHASE REARRANGEMENT CYCLOHEXANONE-OXIME IN EPSILON-CAPROLACTAM ON FERRIERITE-CONTAINING CATALYSTS
    SHIRINSKAYA, LP
    MALASHEVICH, LN
    KOMAROV, VS
    BOLOTNIKOVA, EB
    PISMENNAYA, AV
    DOKLADY AKADEMII NAUK BELARUSI, 1984, 28 (09): : 814 - 816
  • [38] Influence of Na+ on the synthesis of silicalite-1 catalysts for use in the vapor phase Beckmann rearrangement of cyclohexanone oxime
    Yang R.
    Meng F.
    Wang X.
    Wang Y.
    Frontiers of Chemical Science and Engineering, 2011, 5 (4) : 401 - 408
  • [39] Effect of post-treatment of silicalite-1 on its catalytic performance for vapor-phase Beckmann rearrangement of cyclohexanone oxime
    Tao, WC
    Mao, DS
    Chen, QL
    Hu, Y
    CHINESE JOURNAL OF CATALYSIS, 2005, 26 (05) : 417 - 422
  • [40] Synthesis of a novel super-microporous layered material and its catalytic application in the vapor-phase Beckmann rearrangement of cyclohexanone oxime
    Guo, XJ
    Hou, WH
    Ding, WP
    Fan, YN
    Yan, QJ
    Chen, Y
    MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 80 (1-3) : 269 - 274
12345