Organic derivatives of alkylene dithiophosphates part III:: Synthesis and properties of 2-(p-nitrophenyl) and 2-(p-nitrobenzoyl) derivatives of alkylene dithiophosphates

被引：6

作者：

Sharma, CS ^{[1
]}

Sharma, MK ^{[1
]}

Nagar, PN ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2002年 / 177卷 / 04期

关键词：

IR; NMR spectra; O; O '-alkylene dithiophosphates; p-bromonitrobenzene; p-O; O '-alkylene dithiophosphato-(S)-nitro-benzene; p-nitrobenzoyl chloride;

D O I：

10.1080/10426500210659

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of p-bromonitrobenzene and p-nitrobenzoyl chloride with ammonium salt of alkylene dithiophosphates ((OGOPS(2)NH(4): G = -CMe2CMe2-, -CH2CMe2CH2-, -CMe2CH2CHMe-, -CH2CH2 CHMe-) in 1:1 molar ratio in refluxing benzene solution yields: non-volatile yellow colored solids and red colored viscous liquids respectively of the type OGOP(S)SR (R = -C6H4NO2, (O)CC6H4NO2) which are monomeric in nature. The newly synthesized complexes have been characterized by physico-chemical and spectroscopic techniques (M.W, IR, NMR [H-1 and P-31]). On the basis of above studies, the formation of P-S-C and P-S-C(O) chemical bonds has been established.

引用

页码：981 / 987

页数：7

共 50 条

[1] Organic derivatives of alkylene dithiophosphates, part IV:: Synthesis and properties of phenyl acetyl and p-methyl benzoyl derivatives of alkylene dithiophosphates
Sharma, CS
Nagar, PN
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2006, 181 (02) : 453 - 460
[2] p-NITROPHENYL AND p-NITROBENZOYL DERIVATIVES OF O,O′-ALKYLENE DITHIOPHOSPHATE
Chordia, Leena
Chaturvedi, Alok
JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2008, 53 (04): : 1650 - 1652
[3] Organic derivatives of alkylene dithiophosphates. Part II: Synthesis and properties of 2-acetanilide (benzanilide) derivatives of alkylene dithiophosphates
Purwar, R
Sharma, MK
Sharma, RK
Nagar, PN
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 174 : 15 - 23
[4] ORGANIC DERIVATIVES OF ALKYLENE DITHIOPHOSPHATE .1. SYNTHESIS AND PROPERTIES OF 2-ACYL(BENZOYL) ALKYLENE DITHIOPHOSPHATES
PURWAR, R
NAGAR, PN
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1994, 86 (1-4): : 211 - 215
[5] Synthesis and properties of N-bromosuccinimide derivatives of ammonium dialkyl/alkylene dithiophosphates
Harkut, Neelam
Jha, B. K.
Nagar, Padam N.
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2007, 182 (12) : 2801 - 2807
[6] Synthesis and properties of N-bromosuccinimide derivatives of ammonium dialkyl/alkylene dithiophosphates
Harkut, Neelam
Nagar, Padam N.
BIOINORGANIC CHEMISTRY AND APPLICATIONS, 2007, 2007
[7] Synthesis and properties of sulfuryl chloride derivatives of ammonium dialkyl/alkylene dithiophosphates in different molar ratios
Harkut, Neelam
Nagar, Padam N.
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2007, 182 (06) : 1327 - 1334
[8] Synthesis, Characterization, and Biological Evaluation of 2-(p-Nitrophenyl)quinazolin-4(3H)-one Derivatives
V. N. Giradkar
U. D. Kabra
R. S. Diwakar
R. T. Lohiya
M. J. Umekar
Russian Journal of Organic Chemistry, 2020, 56 : 1455 - 1461
[9] Synthesis, Characterization, and Biological Evaluation of 2-(p-Nitrophenyl)quinazolin-4(3H)-one Derivatives
Giradkar, V. N.
Kabra, U. D.
Diwakar, R. S.
Lohiya, R. T.
Umekar, M. J.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 56 (08) : 1455 - 1461
[10] 2-[[(P-NITROPHENYL)SULFONYL]OXY] 3-KETO ESTERS AS INTERMEDIATES FOR THE REGIOSPECIFIC PREPARATION OF 2-[[(P-NITROPHENYL)SULFONYL]OXY] KETONES
HOFFMAN, RV
KIM, HO
LEE, JC
JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (07): : 1933 - 1936

← 1 2 3 4 5 →