Heteroleptic copper(I)-polypyridine complexes as efficient sensitizers for dye sensitized solar cells

被引:93
|
作者
Sandroni, Martina [1 ]
Favereau, Ludovic [1 ]
Planchat, Aurelien [1 ]
Akdas-Kilig, Huriye [2 ]
Szuwarski, Nadine [1 ]
Pellegrin, Yann [1 ]
Blart, Errol [1 ]
Le Bozec, Hubert [2 ]
Boujtita, Mohammed [1 ]
Odobel, Fabrice [1 ]
机构
[1] Univ Nantes, UNAM, CNRS, UMR 6230, F-44322 Nantes 3, France
[2] Univ Rennes 1, CNRS, UMR 6226, Inst Sci Chim Rennes, F-35042 Rennes, France
关键词
COPPER(I); COMPLEXES;
D O I
10.1039/c4ta01755b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis and the physico-chemical characterization of HETPHEN based heteroleptic copper(I)-bis(diimine) complexes are reported. For TiO2 based dye sensitized solar cells (DSCs), the latter display impressive photoconversion efficiencies (PCEs), unprecedented for first row transition metal coordination complexes.
引用
下载
收藏
页码:9944 / 9947
页数:4
相关论文
共 50 条
  • [41] Atypical organic dyes used as sensitizers for efficient dye-sensitized solar cells
    Yue Hu
    Neil Robertson
    Frontiers of Optoelectronics, 2016, 9 (01) : 38 - 43
  • [42] Molecular engineering of zinc phthalocyanine sensitizers for efficient dye-sensitized solar cells
    Ikeuchi, Takuro
    Nomoto, Hirotaka
    Masaki, Naruhiko
    Griffith, Matthew J.
    Mori, Shogo
    Kimura, Mutsumi
    CHEMICAL COMMUNICATIONS, 2014, 50 (16) : 1941 - 1943
  • [43] Novel Organic Sensitizers with a Quinoline Unit for Efficient Dye-sensitized Solar Cells
    Choi, Hyeju
    Choi, Hyunbong
    Paek, Sanghyun
    Song, Kihyung
    Kang, Moon-sung
    Ko, Jaejung
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2010, 31 (01): : 125 - 132
  • [44] New D-A-π-A organic sensitizers for efficient dye-sensitized solar cells
    Li, Xiangguang
    Zheng, Zhiwei
    Jiang, Wei
    Wu, Wenjun
    Wang, Zhaohui
    Tian, He
    CHEMICAL COMMUNICATIONS, 2015, 51 (17) : 3590 - 3592
  • [45] Organic Dye Sensitizers and Their Application in Dye-Sensitized Solar Cells
    Wu Guohua
    Kong Fantai
    Weng Jian
    Dai Songyuan
    Xi Xiaowang
    Zhang Changneng
    PROGRESS IN CHEMISTRY, 2011, 23 (09) : 1929 - 1935
  • [46] Effect of the Ancillary Ligand on the Performance of Heteroleptic Cu(I) Diimine Complexes as Dyes in Dye-Sensitized Solar Cells
    Franchi, Daniele
    Leandri, Valentina
    Pizzichetti, Angela Raffaella Pia
    Xu, Bo
    Hao, Yan
    Zhang, Wei
    Sloboda, Tamara
    Svanstrom, Sebastian
    Cappel, Ute B.
    Kloo, Lars
    Sun, Licheng
    Gardner, James M.
    ACS APPLIED ENERGY MATERIALS, 2022, 5 (02) : 1460 - 1470
  • [47] Ruthenium complexes as sensitizers with phenyl-based bipyridine anchoring ligands for efficient dye-sensitized solar cells
    Huang, Yin
    Chen, Wang-Chao
    Zhang, Xian-Xi
    Ghadari, Rahim
    Fang, Xia-Qin
    Yu, Ting
    Kong, Fan-Tai
    JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (35) : 9445 - 9452
  • [48] Substituted polypyridine complexes of cobalt(II/III) as efficient electron-transfer mediators in dye-sensitized solar cells
    Sapp, SA
    Elliott, CM
    Contado, C
    Caramori, S
    Bignozzi, CA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (37) : 11215 - 11222
  • [49] Are Alkynyl Spacers in Ancillary Ligands in Heteroleptic Bis(diimine)copper(I) Dyes Beneficial for Dye Performance in Dye-Sensitized Solar Cells?
    Risi, Guglielmo
    Becker, Mariia
    Housecroft, Catherine E.
    Constable, Edwin C.
    MOLECULES, 2020, 25 (07):
  • [50] Aminophenyl/carboxyphenylporphyrins as sensitizers for dye-sensitized solar cells
    Rudine, Alexander B.
    Day, Nicholas U.
    Tian, Xisen
    Lee, Chang
    James, Keith E.
    Wamser, Carl C.
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2016, 20 (8-11) : 1217 - 1223