Emulsion polymerization of styrene using polystyrene-block-poly(ethylene oxide) macromonomers as stabilizers

被引：7
|
作者：
Gibanel, S
Heroguez, V
Forcada, J
机构：
[1] Univ Basque Country, EHU, Inst Polymer Mat POLYMAT, San Sebastian 20080, Spain
[2] Univ Basque Country, EHU, Fac Ciencias Quim, Dept Quim Aplicada,Grp Ingn Quim, San Sebastian 20080, Spain
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2002年 / 40卷 / 16期
关键词：
macromonomers; surfactants; diblock copolymers; emulsion polymerization;
D O I：
10.1002/pola.10379
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
New diblock macromonomers were used as reactive emulsifiers in the emulsion polymerization of styrene. The nature of the reactive group, the molecular weight, the length of the poly(ethylene oxide) (PEO) block, and the molecular structure of the macromonomer were systematically investigated during this process by analyzing the evolution of the conversion and particle diameters. (C) 2002 Wiley Periodicals, Inc.
引用
收藏
页码：2819 / 2827
页数：9
相关论文
共 50 条
  • [21] Polystyrene-block-poly(ethylene oxide) stars as surface films at the air/water interface
    Logan, JL
    Masse, P
    Gnanou, Y
    Taton, D
    Duran, RS
    LANGMUIR, 2005, 21 (16) : 7380 - 7389
  • [22] Polystyrene-block-poly(ethylene oxide) from nitroxide mediated polymerization:: detection of minor species by coupled chromatographic techniques
    Beaudoin, E
    Dufils, PE
    Gigmes, D
    Marque, S
    Petit, C
    Tordo, P
    Bertin, D
    POLYMER, 2006, 47 (01) : 98 - 106
  • [23] Radical polymerization kinetics of poly(ethylene oxide) macromonomers
    Nomura, E
    Ito, K
    Kajiwara, A
    Kamachi, M
    MACROMOLECULES, 1997, 30 (10) : 2811 - 2817
  • [24] Structure formation of integral-asymmetric membranes of polystyrene-block-Poly(ethylene oxide)
    Hahn, Janina
    Filiz, Volkan
    Rangou, Sofia
    Clodt, Juliana
    Jung, Adina
    Buhr, Kristian
    Abetz, Clarissa
    Abetz, Volker
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2013, 51 (04) : 281 - 290
  • [25] Structure formation of integral-asymmetric membranes of polystyrene-block-poly(ethylene oxide)
    Hahn, J.
    Filiz, V.
    Rangou, S.
    Clodt, J.
    Jung, A.
    Buhr, K.
    Abetz, C.
    Abetz, V.
    EUROMEMBRANE CONFERENCE 2012, 2012, 44 : 1844 - 1847
  • [26] Interaction of polystyrene-block-poly(ethylene oxide) copolymer with cetylpyridinium chloride in aqueous solution
    Timofeeva, G.I.
    Dubrovina, L.V.
    Bronshtejn, L.M.
    Chernyshov, D.M.
    Bragina, T.P.
    Valetskij, P.M.
    Khokhlov, A.R.
    Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 2001, 43 (06): : 1063 - 1069
  • [27] Amphiphilic poly(ethylene oxide) macromonomers, polymerization and copolymerization
    Ito, K
    Maniruzzaman, M
    Nishimura, H
    Hattori, T
    Tano, K
    Kawaguchi, S
    TAILORED POLYMERS & APPLICATIONS, 2000, : 15 - 23
  • [28] Polystyrene-block-poly(butyl acrylate) and polystyrene-block-poly[(butyl acrylate)-co-styrene] block copolymers prepared via controlled free-radical miniemulsion polymerization using degenerative iodine transfer
    Farcet, C
    Lansalot, M
    Pirri, R
    Vairon, JP
    Charleux, B
    MACROMOLECULAR RAPID COMMUNICATIONS, 2000, 21 (13) : 921 - 926
  • [29] Copolymerization of styrene with nonionic surfactants: Poly(ethylene oxide) macromonomers
    Liu, J
    Chew, CH
    Wong, SY
    Gan, LM
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1996, A33 (09): : 1181 - 1197
  • [30] SOLUBILIZATION OF POLYISOBUTYLENE BY POLYSTYRENE-BLOCK-POLY(ETHYLENE/PROPYLENE) MICELLES
    QUINTANA, JR
    SALAZAR, RA
    KATIME, I
    MACROMOLECULES, 1994, 27 (03) : 665 - 668
12345