Double complex [Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4: Synthesis and crystal structure

被引：0
|
作者：
Cherkasova, T. G. [1 ]
Bagryanskaya, I. Yu. [2 ,3 ]
Pervukhina, N. V. [4 ]
Vornakov, A. L. [1 ]
Cherkasova, E. V. [1 ]
Kuratieva, N. V. [3 ,4 ]
机构：
[1] Kuzbass State Tech Univ, Ul Vesennyaya 28, Kemerovo 650000, Russia
[2] Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
[3] Novosibirsk Natl Res State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia
[4] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 02期
关键词：
CU(II)/CR(III) COMPLEXES; REINECKES SALT; COPPER-POWDER; X-RAY;
D O I：
10.1134/S003602361702005X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Mn-2(C11H13N3O)(6)(H2O)(2)][Cr(NH3)(2)(NCS)(4)](4) (I) has been synthesized by the reaction between MnCl2 center dot H2O, NH4[Cr(NH3)(2)(NCS)(4)] center dot 0.5H(2)O and 4-aminoantipyrine (C11H13N3O) in an aqueous solution, and its structure has been determined by IR spectroscopy and X-ray diffraction. Crystals of complex I are triclinic, space group , Z = 1, a = 13.2378(5) , b = 15.7796(5) , c = 16.7703(6) , alpha = 83.194(2)A degrees, beta = 75.874(2)A degrees, gamma = 66.529(1)A degrees, V = 3115.2(2) (3), and rho(calcd) = 1.407 g/cm(3).
引用
收藏
页码：182 / 186
页数：5
相关论文
共 50 条
  • [21] Synthesis and structure of three manganese oxalates:: MnC2O4 • 2H2O, [C4H8(NH2)2][Mn2(C2O4)3] and Mn2(C2O4)(OH)2
    Lethbridge, ZAD
    Congreve, AF
    Esslemont, E
    Slawin, AMZ
    Lightfoot, P
    JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (01) : 212 - 218
  • [22] Synthesis and structure of (NH4)3[UO2(C3H2O4)2(NCS)] · 2H2O
    L. B. Serezhkina
    E. V. Peresypkina
    A. V. Virovets
    Ya. A. Medvedkov
    V. N. Serezhkin
    Crystallography Reports, 2014, 59 : 48 - 52
  • [23] Mixed inorganic-organic anion frameworks:: synthesis and characterisation of [Mn4(PO4)2(C2O4)(H2O)2] and [H3N(CH2)3NH3][Mn2(HPO4)2(C2O4)(H2O)2]
    Lethbridge, ZAD
    Hillier, AD
    Cywinski, R
    Lightfoot, P
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (10): : 1595 - 1599
  • [24] Double Complex Salts [Ln(C6H5NO2)3(H2O)2][Cr(NCS)6] • 2H2O (Ln = Lu, Ce, Y): Synthesis and Crystal Structure
    Cherkasova, E., V
    Pervukhina, N., V
    Kuratieva, N., V
    Cherkasova, T. G.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (03) : 329 - 334
  • [25] Double Complex Salts [Ln(C6H5NO2)3(H2O)2][Cr(NCS)6] · 2H2O (Ln = Lu, Ce, Y): Synthesis and Crystal Structure
    E. V. Cherkasova
    N. V. Pervukhina
    N. V. Kuratieva
    T. G. Cherkasova
    Russian Journal of Inorganic Chemistry, 2019, 64 : 329 - 334
  • [26] Synthesis and crystal structure of Zn[(C6H5N3)4(H2O)2](ClO4)2 and Cu[(C6H5N3)4(H2O)2](CIO4)2
    Li, LX
    Wang, XQ
    Shen, GQ
    Wang, RJ
    Shen, DZ
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (07) : 453 - 457
  • [27] Synthesis and crystal structure of [Zn(H2O)4(C4H2O4)] • H2O
    XIe, HZ
    Zheng, YQ
    Shou, KQ
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (15) : 1291 - 1297
  • [28] (NH4)(CN3H6)2[UO2(C2O4)2(NCS)] • 2H2O:: Synthesis and crystal structure
    Akhmerkina, Zh. V.
    Virovets, A. V.
    Peresypkina, E. V.
    Serezhkina, L. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (02) : 229 - 234
  • [29] (NH4)(CN3H6)2[UO2(C2O4)2(NCS)] · 2H2O: Synthesis and crystal structure
    Zh. V. Akhmerkina
    A. V. Virovets
    E. V. Peresypkina
    L. B. Serezhkina
    Russian Journal of Inorganic Chemistry, 2006, 51 : 229 - 234
  • [30] Synthesis and structure of [Nd(C6NO2H5)3(H2O)2]2n • (3nHgCl4) • (4nH2O)
    Fang, Xiao-Niu
    Chen, Wen-Tong
    Xu, Ya-Ping
    Luo, Qiu-Yan
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2009, 224 (03): : 169 - 173
12345