Double complex [Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4: Synthesis and crystal structure

被引：0
|
作者：
Cherkasova, T. G. [1 ]
Bagryanskaya, I. Yu. [2 ,3 ]
Pervukhina, N. V. [4 ]
Vornakov, A. L. [1 ]
Cherkasova, E. V. [1 ]
Kuratieva, N. V. [3 ,4 ]
机构：
[1] Kuzbass State Tech Univ, Ul Vesennyaya 28, Kemerovo 650000, Russia
[2] Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
[3] Novosibirsk Natl Res State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia
[4] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 02期
关键词：
CU(II)/CR(III) COMPLEXES; REINECKES SALT; COPPER-POWDER; X-RAY;
D O I：
10.1134/S003602361702005X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Mn-2(C11H13N3O)(6)(H2O)(2)][Cr(NH3)(2)(NCS)(4)](4) (I) has been synthesized by the reaction between MnCl2 center dot H2O, NH4[Cr(NH3)(2)(NCS)(4)] center dot 0.5H(2)O and 4-aminoantipyrine (C11H13N3O) in an aqueous solution, and its structure has been determined by IR spectroscopy and X-ray diffraction. Crystals of complex I are triclinic, space group , Z = 1, a = 13.2378(5) , b = 15.7796(5) , c = 16.7703(6) , alpha = 83.194(2)A degrees, beta = 75.874(2)A degrees, gamma = 66.529(1)A degrees, V = 3115.2(2) (3), and rho(calcd) = 1.407 g/cm(3).
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页码：182 / 186
页数：5
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