Tris(S,S-dioxide)-trithiasumanene: strong fluorescence and cocrystal with 1,2,6,7,10,11-hexabutoxytriphenylene

被引：36
|
作者：
Hou, Xueqing [1 ]
Zhu, Yongtao [1 ]
Qin, Yunke [2 ]
Chen, Lichuan [1 ]
Li, Xuexiang [1 ]
Zhang, Hao-Li [1 ]
Xu, Wei [2 ]
Zhu, Daoben [2 ]
Shao, Xiangfeng [1 ]
机构：
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Tianshui Southern Rd 222, Lanzhou, Gansu, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100180, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 09期
基金：
中国国家自然科学基金;
关键词：
ENANTIOSELECTIVE SYNTHESIS; ELECTRONIC-PROPERTIES; AROMATIC SADDLES; SOLID-STATE; OLIGOTHIOPHENES; OXIDATION; THIOPHENE; DERIVATIVES; SUMANENE; DESIGN;
D O I：
10.1039/c6cc09531c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Thiophene rings in trithiasumanene (1) are oxidized regioselectively to formtris(S,S-dioxide)-trithiasumanene (3). Compound 3 displays strong indigo fluorescence in both solution and the solid state, and forms a 1 : 1 cocrystal with HBT to give a yellow emission in crystalline form.
引用
收藏
页码：1546 / 1549
页数：4
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