Tris(S,S-dioxide)-trithiasumanene: strong fluorescence and cocrystal with 1,2,6,7,10,11-hexabutoxytriphenylene

被引：36

作者：

Hou, Xueqing ^{[1
]}

Zhu, Yongtao ^{[1
]}

Qin, Yunke ^{[2
]}

Chen, Lichuan ^{[1
]}

Li, Xuexiang ^{[1
]}

Zhang, Hao-Li ^{[1
]}

Xu, Wei ^{[2
]}

Zhu, Daoben ^{[2
]}

Shao, Xiangfeng ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Tianshui Southern Rd 222, Lanzhou, Gansu, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100180, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 09期

基金：

中国国家自然科学基金;

关键词：

ENANTIOSELECTIVE SYNTHESIS; ELECTRONIC-PROPERTIES; AROMATIC SADDLES; SOLID-STATE; OLIGOTHIOPHENES; OXIDATION; THIOPHENE; DERIVATIVES; SUMANENE; DESIGN;

D O I：

10.1039/c6cc09531c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thiophene rings in trithiasumanene (1) are oxidized regioselectively to formtris(S,S-dioxide)-trithiasumanene (3). Compound 3 displays strong indigo fluorescence in both solution and the solid state, and forms a 1 : 1 cocrystal with HBT to give a yellow emission in crystalline form.

引用

页码：1546 / 1549

页数：4

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