Study of an EE mechanism using double potential step techniques

被引：14
|
作者：
López-Tenes, M [1 ]
Moreno, MM [1 ]
Serna, C [1 ]
Molina, A [1 ]
机构：
[1] Univ Murcia, Fac Quim, Dept Quim Fis, ESP-30100 Murcia, Spain
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2002年 / 528卷 / 1-2期
关键词：
EE mechanism; voltammetry; polarography; double potential step techniques;
D O I：
10.1016/S0022-0728(02)00904-X
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
An analytical solution corresponding to the double potential step problem for a reversible EE mechanism is presented. This solution is applicable to any double pulse technique without restrictions on the duration of the first and second potential steps and is valid when several species are initially present in the solution. The influence of the duration of the two pulses on the characteristic of the current-potential curves on differential and reverse double pulse techniques in static and dynamic electrodes is also discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：159 / 169
页数：11
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