Polymerization of Furylthiazoles with Palladium-Catalyzed Direct Arylation Polycondensation

被引：1
|
作者：
Ashida, Kana [1 ]
Murase, Yuki [1 ]
Miyagawa, Naoki [1 ]
Okano, Kentaro [1 ]
Mori, Atsunori [1 ]
机构：
[1] Kobe Univ, Dept Chem Sci & Engn, Nada Ku, 1-1 Rokkodai, Kobe, Hyogo 6578501, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2017年 / 90卷 / 05期
关键词：
DESIGN; ACID;
D O I：
10.1246/bcsj.20170027
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Effective transformation of a biomass-derived heteroaromatic compound furfural into conjugated polymer is described. Furylthiazole composed of furan and thiazole rings is employed as a monomer and palladium-catalyzed C-H coupling polycondensation furnishes the corresponding formal alternating copolymer. The coupling reaction in the presence of Pd(OAc)(2) (20mol%) as a catalyst undergoes polymerization in >99% yield with M-n = 10.2 x 10(3).
引用
收藏
页码：565 / 567
页数：3
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