Synthesis and structure of the first transition metal complex with methanesulfonylhydrazine as a ligand

被引：0
|
作者：
Ienco, A
Mealli, C
Dodoff, NI
机构：
[1] CNR, ICCOm, I-50139 Florence, Italy
[2] Bulgarian Acad Sci, Inst Mol Biol, Sofia 1113, Bulgaria
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2002年 / 57卷 / 08期
关键词：
methanesulfonylhydrazine; zinc complex; X-ray structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The article reports the first transition metal complex of methanesulfonylhydrazine, a molecule known for important pharmacological and chemical applications. The complex [ZnCl2(MSH)(2)], MSH = CH3SO2NHNH2, has been synthesized and its structure characterized by means of Xray analysis. The coordination geometry is pseudo-tetrahedral and the ligand MSH adopts a conformation that was found by previous ab initio calculations to be a transition state and not a stationary point for the free ligand.
引用
收藏
页码：865 / 867
页数：3
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