Catalytic conversion of methanol to olefins over rare earth (La, Y) modified SAPO-34

被引：24
|
作者：
Lu, Jinzhao [1 ]
Wang, Xinping [1 ]
Li, Hongbin [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2009年 / 97卷 / 02期
关键词：
Rare earth modification; MTO; SAPO-34; Light olefins; MOLECULAR-SIEVES; NICKEL INCORPORATION; MTO PROCESS; ZEOLITE; HYDROCARBONS; STABILITY; SILICON; SITES;
D O I：
10.1007/s11144-009-0046-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
SAPO-34 modified with lanthanum and yttrium exhibited higher selectivity to light olefins, lower methane formation, and longer lifetime (prolonged by 20%) than the parent SAPO-34 in the process of methanol conversion to olefins. The modified catalytic performance could be ascribed to the incorporation of La3+ and Y3+ into the framework of SAPO-34.
引用
收藏
页码：255 / 261
页数：7
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