Syntheses and crystal structures of some CCo3 clusters containing PPh3 or dppm Ligands

被引：22

作者：

Bruce, MI ^{[1
]}

Kramarczuk, KA

Perkins, GJ

Skelton, BW

White, AH

Zaitseva, NN

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

[2] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia

来源：

JOURNAL OF CLUSTER SCIENCE | 2004年 / 15卷 / 02期

关键词：

cobalt carbide clusters; X-ray structures; tertiary phosphine complexes; amido; carboxylate;

D O I：

10.1023/B:JOCL.0000027397.89365.42

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Molecular structural determinations are reported for six Co3C carbonyl cluster complexes containing tertiary phosphines, which have been isolated as by-products from a variety of reactions. Structural features are similar to those of related complexes already reported. Some discussion of apparent orientational preferences of the CH2 group of dppm ligands, which appear to enter into H-bonding interactions with amido or carboxylate substituents, is given. Appropriate comparisons are made with unsubstituted analogues.

引用

页码：119 / 137

页数：19

共 50 条

[21] REACTION OF NI-8-CLUSTERS WITH SODIUM AMALGAM - THE CRYSTAL-STRUCTURES OF ([NI8HG(PPH)6(PPH3)4].[NI8(PPH)6(PPH3)4]) AND [NI8S6(PPH3)8]
FENSKE, D
MAGULL, J
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (02): : 121 - 126
[22] THE CHEMISTRY OF HETEROALLYL DERIVATIVES OF TECHNETIUM - REACTIVITY OF [TCNCL2(PPH3)2] AND [TC(CO)3CL(PPH3)] WITH THIAZETIDINE LIGANDS, CRYSTAL-STRUCTURES OF [TC(CO)2(PPH3)2(PHN=C(OET)S)] AND [TCN(CL)(PPH3)-(PHN=C(OET)S)]
ROSSI, R
MARCHI, A
AGGIO, S
MAGON, L
DUATTI, A
CASELLATO, U
GRAZIANI, R
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (02): : 477 - 481
[23] Syntheses and crystal structures of [(AMTTO)Pd(PPh3)Cl]Cl•MeOH and [(AMTTO)Pd(SCN)2]•MeCN
Neumüller, B
Heravi, MM
Ghassemzadeh, M
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (11): : 1908 - 1911
[24] SYNTHESES, PROPERTIES AND X-RAY CRYSTAL-STRUCTURES OF HEXANUCLEAR COBALT - CHALCOGEN CLUSTERS CO6S8(PPH3)6 AND CO6SE8(PPH3)6.THF
HONG, MC
HUANG, ZY
LEI, XJ
WEI, GW
KANG, BS
LIU, HQ
POLYHEDRON, 1991, 10 (09) : 927 - 934
[25] STRUCTURAL COMPARISON OF CLUSTER COMPOUNDS CONTAINING AN EDGE-BRIDGING CU(PPH3), AG(PPH3), AU(PPH3) FRAGMENT - X-RAY CRYSTAL-STRUCTURE OF [AGRU3(CO)9(C2BUT)(PPH3)]
ADATIA, T
MCPARTLIN, M
SALTER, ID
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (11): : 2889 - 2891
[26] SYNTHESIS AND REACTIONS OF [(OC)3FE(MU-DPPM)(MU-CO)PT(PPH3)] WITH ACETYLENES OR ALLENE - CRYSTAL-STRUCTURES OF [(OC)3FE(MU-DPPM)(MU-CO)PT(PPH3)], [(OC)2FE(MU-DPPM)(MU-SIGMA-ETA-3-C(O)C2H2)PT(PPH3)], AND [(OC)3FE(MU-DPPM)(MU-CH2C(=CH2))PT(PPH3)] (DPPM = PH2PCH2PPH2)
FONTAINE, XLR
JACOBSEN, GB
SHAW, BL
THORNTONPETT, M
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (09) : 662 - 664
[27] Syntheses, characterization, and structures of three ruthenium complexes containing two monodentate dppm ligands
Yu, Yu-Li
Huang, Li-Hong
Zhou, Yi-Feng
Lou, Ji-Dong
Lu, Xiu Lian
JOURNAL OF COORDINATION CHEMISTRY, 2014, 67 (07) : 1208 - 1218
[28] Triosmium clusters containing bridging dppm and PhSe ligands:: X-ray crystal structure of [(μ-H)Os3(CO)8( μ-SePh)(μ-dppm)]
Begum, N
Hassan, MM
Kabir, SE
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2005, 44 (03): : 490 - 496
[29] Synthesis and Characterization of the (μ3-CR)Co3 Tetrahedral Carbonyl Clusters Containing (μ3,η3-(PPh2CH2)3CCH3) Ligand and the Crystal Structure of Cluster (μ3-CPh)CCo3(CO)3(μ-CO)3 (μ3,η3-(PPh2CH2)3 CCH3)
Bao-Hua Zhu
Shuang-Yu Gao
Yan-Hong Bai
Journal of Cluster Science, 2008, 19 : 171 - 179
[30] A NEW COPPER SELENIDE CLUSTER WITH PPH3 LIGANDS - [CU146SE73(PPH3)30]
KRAUTSCHEID, H
FENSKE, D
BAUM, G
SEMMELMANN, M
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (09): : 1303 - 1305

← 1 2 3 4 5 →