Visible-Light-Induced Organocatalytic Borylation of Aryl Chlorides

被引：105
|
作者：
Zhang, Li [1 ]
Jiao, Lei [1 ]
机构：
[1] Tsinghua Univ, Dept Chem, Ctr Basic Mol Sci, Beijing 10084, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 23期
基金：
中国国家自然科学基金;
关键词：
METAL-FREE BORYLATION; ALKOXY DIBORON REAGENTS; FREE REDUCTIVE CLEAVAGE; ELECTRON-TRANSFER; CATALYZED BORYLATION; HALIDES; TRANSITION; BOND; ACTIVATION; IODIDES;
D O I：
10.1021/jacs.9b00917
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The preparation of arylboronates from unactivated aryl chlorides in a transition-metal-free manner is rather challenging. There are only few examples to achieve this goal by using ultraviolet irradiation. Based on the mechanistic understanding of the diboron/methoxide/pyridine reaction system, we achieved photo activation of the in situ generated super electron donor and developed a visible-light-induced organocatalytic method for efficient borylation of unactivated aryl chlorides.
引用
收藏
页码：9124 / 9128
页数：5
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