Liquid-vapor equilibrium and ionization of HCl in the system HCl-H2SO4-H2O at 298 K

被引：2
|
作者：
Poltoratskii, GM [1 ]
Andreev, SB [1 ]
Osovskaya, II [1 ]
Yakovlev, VA [1 ]
机构：
[1] St Petersburg State Technol Univ Plant Polymers, St Petersburg, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
H2SO4; Dissociation Constant; Infinite Dilution; Equilibrium Pressure; Fixed Concentration;
D O I：
10.1023/A:1021649106857
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The equilibrium pressures and compositions of the vapor over HCl-H2SO4-H2O solutions with a low content of HCl and several fixed concentrations of H2SO4 were measured by the flow method at 298 K. The "semiconcentration" values of the mixed dissociation constants of HCl were calculated and extrapolated to infinite dilution.
引用
收藏
页码：1339 / 1342
页数：4
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