Green Aqueous Wittig Reaction: Teaching Green Chemistry in Organic Teaching Laboratories

被引:24
|
作者
Morsch, Layne A. [1 ]
Deak, Leanne [1 ]
Tiburzi, Dyllan [1 ]
Schuster, Harrison [1 ]
Meyer, Brittney [1 ]
机构
[1] Univ Illinois, Dept Chem, Springfield, IL 62703 USA
关键词
Second-Year Undergraduate; Organic Chemistry; Laboratory Instruction; Green Chemistry; Aldehydes; Aqueous Solution Chemistry; Reactions; EMPLOYING STABILIZED YLIDES; ETHYL TRANS-CINNAMATE; ALDEHYDES; SOLVENT; EFFICIENT; WATER;
D O I
10.1021/ed400408k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Green experiments in the organic teaching lab are a vital part of training a new generation of scientists. Not only do they make the lab experience safer and produce less costly waste, they allow students an opportunity to examine and consider potentially hazardous chemical methodologies and develop alternatives. The work discussed here focuses on a series of Wittig reactions that are carried out in aqueous conditions, at room temperature, and in less than one hour. The reactions have been applied to a variety of starting aldehydes. Results for this work and strategies for implementing a green chemistry case study into the laboratory curriculum are presented.
引用
收藏
页码:611 / 614
页数:4
相关论文
共 50 条
  • [41] Teaching green chemistry and sustainability with PhET Interactive Simulations
    Chamberlain, Julia M.
    Carpenter, Yuen-ying
    Loeblein, Patricia
    Perkins, Katherine K.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [42] Teaching green chemistry: from lemons to lemonade bottles
    Tavener, S
    Hardy, J
    Hart, N
    Goddard, A
    [J]. GREEN CHEMISTRY, 2003, 5 (03) : G46 - G48
  • [43] Web-based green chemistry teaching modules
    Cann, Michael C.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 232 : 762 - 762
  • [44] GREEN CHEMISTRY - FROM ITS BIRTH TO ITS TEACHING
    Machado, Adelio A. S. C.
    [J]. QUIMICA NOVA, 2011, 34 (03): : 535 - 543
  • [45] The EcoScale as a framework for undergraduate green chemistry teaching and assessment
    Dicks, Andrew P.
    Hent, Andrei
    Koroluk, Katherine J.
    [J]. GREEN CHEMISTRY LETTERS AND REVIEWS, 2018, 11 (01) : 29 - 35
  • [46] Beyond the Deficit Model: Organic Chemistry Educators' Beliefs and Practices about Teaching Green and Sustainable Chemistry
    Parker, Alexandria
    Noronha, Evan
    Bongers, Amanda
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2023, 100 (05) : 1728 - 1738
  • [47] YCC 14-Green chemistry in the organic chemistry teaching lab: Benefits, challenges and lessons learned
    Hutchison, James E.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [48] The Sustainability Challenges Facing Research and Teaching Laboratories When Going Green
    Banks, Marcus
    Metz, Molly
    Smyth, Davida S.
    [J]. ENVIRONMENT, 2020, 62 (02): : 4 - 13
  • [49] The state of organic teaching laboratories
    Horowitz, Gail
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2007, 84 (02) : 346 - 353
  • [50] A Survey of the Practices, Procedures, and Techniques in Undergraduate Organic Chemistry Teaching Laboratories
    Martin, Christopher B.
    Schmidt, Monica
    Soniat, Michael
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2011, 88 (12) : 1630 - 1638