Green Aqueous Wittig Reaction: Teaching Green Chemistry in Organic Teaching Laboratories

被引:24
|
作者
Morsch, Layne A. [1 ]
Deak, Leanne [1 ]
Tiburzi, Dyllan [1 ]
Schuster, Harrison [1 ]
Meyer, Brittney [1 ]
机构
[1] Univ Illinois, Dept Chem, Springfield, IL 62703 USA
关键词
Second-Year Undergraduate; Organic Chemistry; Laboratory Instruction; Green Chemistry; Aldehydes; Aqueous Solution Chemistry; Reactions; EMPLOYING STABILIZED YLIDES; ETHYL TRANS-CINNAMATE; ALDEHYDES; SOLVENT; EFFICIENT; WATER;
D O I
10.1021/ed400408k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Green experiments in the organic teaching lab are a vital part of training a new generation of scientists. Not only do they make the lab experience safer and produce less costly waste, they allow students an opportunity to examine and consider potentially hazardous chemical methodologies and develop alternatives. The work discussed here focuses on a series of Wittig reactions that are carried out in aqueous conditions, at room temperature, and in less than one hour. The reactions have been applied to a variety of starting aldehydes. Results for this work and strategies for implementing a green chemistry case study into the laboratory curriculum are presented.
引用
收藏
页码:611 / 614
页数:4
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