Bis(diazasilaphosphetidines) and their metal complexes

被引：2

作者：

Lief, GR ^{[1
]}

Schranz, I ^{[1
]}

Stahl, L ^{[1
]}

机构：

[1] Univ N Dakota, Dept Chem, Grand Forks, ND 58202 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2004年 / 179卷 / 4-5期

关键词：

bis(diazasilaphosphetidines); bis(phosphines); diazadiphosphetidines; P; N-heterocycles; Si; N; P-heterocycles;

D O I：

10.1080/10426500490427213

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and solid-state structures of bis(diazasilaphosphetidines) of the type [Me2Si(mu-(NBu)-Bu-t)(2)P](2)NR, R = Ph, Pr-i, Bu-t, of the P-chiral analogue [Me2Si(mu-(NBu)-Bu-t)(mu-N-2,6-(PrPh)-Pr-i)P](2)(C2H4), and of some of their metal complexes are reported. The highly electron-rich, modular bis(phosphines) are easy to synthesize and may have applications in catalysis.

引用

页码：813 / 816

页数：4

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