Bis(diazasilaphosphetidines) and their metal complexes

被引:2
|
作者
Lief, GR [1 ]
Schranz, I [1 ]
Stahl, L [1 ]
机构
[1] Univ N Dakota, Dept Chem, Grand Forks, ND 58202 USA
关键词
bis(diazasilaphosphetidines); bis(phosphines); diazadiphosphetidines; P; N-heterocycles; Si; N; P-heterocycles;
D O I
10.1080/10426500490427213
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The syntheses and solid-state structures of bis(diazasilaphosphetidines) of the type [Me2Si(mu-(NBu)-Bu-t)(2)P](2)NR, R = Ph, Pr-i, Bu-t, of the P-chiral analogue [Me2Si(mu-(NBu)-Bu-t)(mu-N-2,6-(PrPh)-Pr-i)P](2)(C2H4), and of some of their metal complexes are reported. The highly electron-rich, modular bis(phosphines) are easy to synthesize and may have applications in catalysis.
引用
收藏
页码:813 / 816
页数:4
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