Combined evaluation of nitrocellulose-based propellants: toxicity, performance, and erosivity

被引：26
|
作者：
Mendonca-Filho, L. G. [1 ]
Rodrigues, R. L. B. [1 ]
Rosato, R. [2 ]
Galante, E. B. F. [1 ]
Nichele, J. [1 ,3 ]
机构：
[1] Mil Inst Engn, Chem Engn Dept, Praca Gen Tiburcio 80,Room 3063, BR-22290270 Rio De Janeiro, RJ, Brazil
[2] Companhia Brasileira Cartuchos, Ribeirao Pires, SP, Brazil
[3] Mil Inst Engn, Def Engn Grad Program, Rio De Janeiro, RJ, Brazil
来源：
JOURNAL OF ENERGETIC MATERIALS | 2019年 / 37卷 / 03期
关键词：
Propellants; low toxicity; erosivity; nitrocellulose; closed vessel; HEAT-LOSS; DIPHENYLAMINE; DERIVATIVES; PREDICTION;
D O I：
10.1080/07370652.2019.1606867
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
New formulations of nitrocellulose-based propellants were evaluated aiming less-toxicity-and-less-erosivity. Three original ingredients of M-14 propellant - dinitrotoluene, dibutyl phthalate, and diphenylamine - were replaced. The new formulations, with ballistic performances similar to M-14, were based on ethylcentralite, akardite-II, RDX, diethylene glycol dinitrate, triethylene glycol dinitrate, and acetyl tributyl citrate (ATBC). The toxicities of the crude ingredients were analyzed. The H-2 content in the combustion products was a key point in the analysis. The best results were found to the compositions based on ATBC and akardite-II only. The work can be used to guide future works related to new formulations of propellants.
引用
收藏
页码：293 / 308
页数：16
相关论文
共 50 条
  • [11] Effect of relative humidity and absorbed water on the ethyl centralite consumption in nitrocellulose-based propellants
    Filipe Poletto Teixeira
    Aline Cardoso Anastacio
    Letivan Gonçalves de Mendonça-Filho
    Jakler Nichele
    Cellulose, 2023, 30 : 1411 - 1420
  • [12] The danger of nitrocellulose-based radiographic films
    de Bruin, DG
    ACTA RADIOLOGICA, 1932, 13 (01) : 80 - 86
  • [13] Can green nitrocellulose-based propellants be made through the replacement of diphenylamine by the natural product curcumin?
    Rodrigues, Rodrigo Leonard Barboza
    Gomes Buitrago, Pedro Augusto
    Nakano, Nami Lavigne
    Peixoto, Fernando Cunha
    Lemos, Mauricio Ferrapontoff
    Franca, Tanos Celmar Costa
    Mendonca Filho, Letivan Goncalvez
    JOURNAL OF ENERGETIC MATERIALS, 2022, 40 (02) : 218 - 241
  • [14] Synthesis and stabilization mechanism of novel stabilizers for fullerene-malonamide derivatives in nitrocellulose-based propellants
    Li, Guang
    Jin, Bo
    Chai, Zuohu
    Liao, Ling
    Chu, Shijin
    Peng, Rufang
    POLYMER TESTING, 2020, 86
  • [15] Direct Ink Writing and Properties of Nitrocellulose-based Gun Propellants Embedded with Multi-cubic Pores
    Fan W.-R.
    Xiong P.
    Song Y.-F.
    Xiao L.-Q.
    Zhao Q.-L.
    Li C.-Z.
    Zhou W.-L.
    Hanneng Cailiao/Chinese Journal of Energetic Materials, 2022, 30 (09): : 903 - 910
  • [16] Erosivity and Performance of Nitrogen-Rich Propellants
    Lavoie, Jonathan
    Petre, Catalin-Florin
    Dubois, Charles
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2018, 43 (09) : 879 - 892
  • [17] PREDICTION OF TOXICITY OF THE USUAL STABILIZERS IN NITROCELLULOSE BASED PROPELLANTS AND THEIR MAIN DEGRADATION PRODUCTS
    Rodrigues, Rodrigo L. B.
    Nichele, Jakler
    Franca, Tanos C. C.
    Mendonca Filho, Letivan G.
    QUIMICA NOVA, 2018, 41 (08): : 867 - 873
  • [18] NITROCELLULOSE-BASED ASSAYS FOR THE DETECTION OF GLYCOLIPIDS AND OTHER ANTIGENS - MECHANISM OF BINDING TO NITROCELLULOSE
    HANDMAN, E
    JARVIS, HM
    JOURNAL OF IMMUNOLOGICAL METHODS, 1985, 83 (01) : 113 - 123
  • [19] Nitrocellulose-based SERS immunosensor for detection of biological molecules
    Dykes, A. C.
    Kamemoto, L.
    Misra, A. K.
    Sharma, S. K.
    SMART BIOMEDICAL AND PHYSIOLOGICAL SENSOR TECHNOLOGY VIII, 2011, 8025
  • [20] THE NON-FICKIAN DIFFUSION OF DETERRENTS INTO A NITROCELLULOSE-BASED PROPELLANT
    WINKLER, DA
    STARKS, A
    JOURNAL OF APPLIED POLYMER SCIENCE, 1988, 35 (01) : 51 - 62
12345